Сумпор диоксигеназа
| Sumpor dioksigenaza | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifikatori | |||||||||
| EC broj | 1.13.11.18 | ||||||||
| CAS broj | 37256-58-9 | ||||||||
| Baze podataka | |||||||||
| IntEnz | IntEnz pregled | ||||||||
| BRENDA | BRENDA pristup | ||||||||
| ExPASy | NiceZyme pregled | ||||||||
| KEGG | KEGG pristup | ||||||||
| MetaCyc | metabolički put | ||||||||
| PRIAM | profil | ||||||||
| Strukture PBP | RCSB PDB PDBe PDBj PDBsum | ||||||||
| |||||||||
Sumpor dioksigenaza (EC 1.13.11.18, sumporna oksigenaza, sumpor:kiseonik oksidoreduktaza) je enzim sa sistematskim imenom S-sulfanilglutation:kiseonik oksidoreduktaza.[1][2] Ovaj enzim katalizuje sledeću hemijsku reakciju
- sumpor + O2 +H2O sulfit + 2 H+ (sveukupna reakcija)
- (1a) glutation + sumpor S-sulfanilglutation (spontana reakcija)
- (1b) S-sulfanilglutation + O2 + H2O glutation + sulfit + 2 H+
Ovaj enzim sadrži gvožđe. Glutation (GSH) ima katalitičku ulogu u aktivaciji elemernog sumpora, ali se ne konzumira tokom reakcije.
Reference[уреди | уреди извор]
- ^ Suzuki, I. & Silver, M. (1966). „The initial product and properties of the sulfur-oxidizing enzyme of thiobacilli”. Biochim. Biophys. Acta. 122: 22—33. PMID 5968172.
- ^ Rohwerder, T. & Sand, W. (2003). „The sulfane sulfur of persulfides is the actual substrate of the sulfur-oxidizing enzymes from Acidithiobacillus and Acidiphilium spp”. Microbiology. 149: 1699—1710. PMID 12855721.
Literatura[уреди | уреди извор]
- Nicholas C. Price; Lewis Stevens (1999). Fundamentals of Enzymology: The Cell and Molecular Biology of Catalytic Proteins (Third изд.). USA: Oxford University Press. ISBN 019850229X.
- Eric J. Toone (2006). Advances in Enzymology and Related Areas of Molecular Biology, Protein Evolution (Volume 75 изд.). Wiley-Interscience. ISBN 0471205036.
- Branden C; Tooze J. Introduction to Protein Structure. New York, NY: Garland Publishing. ISBN 0-8153-2305-0.
- Irwin H. Segel. Enzyme Kinetics: Behavior and Analysis of Rapid Equilibrium and Steady-State Enzyme Systems (Book 44 изд.). Wiley Classics Library. ISBN 0471303097.
- William P. Jencks (1987). Catalysis in Chemistry and Enzymology. Dover Publications. ISBN 0486654605.
Spoljašnje veze[уреди | уреди извор]
- Sulfur+dioxygenase на US National Library of Medicine Medical Subject Headings (MeSH)
