Heksogen
|
|||
| Nazivi | |||
|---|---|---|---|
| IUPAC naziv
1,3,5-Trinitroperhidro-1,3,5-triazin
|
|||
| Drugi nazivi
RDX
ciklonit 1,3,5-Trinitro-1,3,5-triazacikloheksan 1,3,5-Trinitroheksahidro-s-triazin Ciklotrimetilenetrinitramin |
|||
| Identifikacija | |||
|
3D model (Jmol)
|
|||
| ChEBI | |||
| ChemSpider | |||
| ECHA InfoCard | 100.004.092 | ||
| UN broj | 0072, 0391, 0483 | ||
|
|||
| Svojstva | |||
| C3H6N6O6 | |||
| Molarna masa | 222,12 g·mol−1 | ||
| Agregatno stanje | Bezbojni kristali | ||
| Gustina | 1,82 g/cm3 | ||
| Tačka topljenja | 2.055 °C (3.731 °F; 2.328 K) | ||
| Tačka ključanja | 234 °C (453 °F; 507 K) | ||
| Explosive data | |||
| Osetljivost na šok | Nizak | ||
| Osetljivost na trenje | Nizak | ||
| RE faktor | 1,60 | ||
| Opasnosti | |||
| Opasnost u toku rada | Eksploziv | ||
|
Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje materijala (na 25 °C [77 °F], 100 kPa).
|
|||
 verifikuj (šta je   ?) |
|||
| Reference infokutije | |||
Heksogen (RDX) je eksplozivni nitroamin sa širokim spektrom vojnih i industrijskih upotreba. On je razvijen kao eksploziv koji je moćniji od TNT-a i u znatnoj meri je korišten tokom Drugog svetskog rata. Heksogen je takođe poznat kao ciklonit (posebno na nemačkom govornom području), i T4. Njegovo hemijsko ime je ciklotrimetilentrinitramin (ciklotrimetilen-trinitramin, ciklotrimetilen trinitramin).
U svom čistom stanju RDX je bela kristalna materija. On se često koristi u smeši sa drugim eksplozivima i plastifikatorima. RDX je stabilan tokom skladištenja i smatra se jednim od najmoćnijih i najrazornijih eksploziva.[3]
Reference[уреди]
- ↑ Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today. 15 (23-24): 1052—7. PMID 20970519. doi:10.1016/j.drudis.2010.10.003.
- ↑ Evan E. Bolton; Yanli Wang; Paul A. Thiessen; Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry. 4: 217—241. doi:10.1016/S1574-1400(08)00012-1.
- ↑ Department of the Army Technical Manual TM 9-1300-214: Military Explosives. Headquarters, Department of the Army (United States).
Literatura[уреди]
- Akhavan, Jacqueline (2004), The Chemistry of Explosives, Cambridge, UK: Royal Society of Chemistry, ISBN 0-85404-640-2
- Agrawal, Jai Prakhash.; Hodgson, Robert Dale (2007), Organic Chemistry of Explosives, Wiley, ISBN 978-0-470-02967-1
- Bachmann, W. E.; Sheehan, John C. (1949), „A New Method of Preparing the High Explosive RDX”, Journal of the American Chemical Society, 71 (5): 1842—1845, doi:10.1021/ja01173a092
- US 2680671, Bachmann, Werner E., "Method of Treating Cyclonite Mixtures", published 16. 7. 1943., issued 8. 6. 1954.
- US 2798870, Bachmann, Werner E., "Method for Preparing Explosives", published 16. 7. 1943., issued 9. 7. 1957.
- Baxter III, James Phinney (1968) [1946], Scientists Against Time (MIT Paperback изд.), Cambridge, MA: MIT Press, OCLC 476611116, ISBN 978-0-262-52012-6
- Cocroft, Wayne D. (2000). Dangerous Energy: The archaeology of gunpowder and military explosives manufacture. Swindon: English Heritage. ISBN 1-85074-718-0.
- Cooper, Paul W. (1996), Explosives Engineering, New York: Wiley-VCH, ISBN 0-471-18636-8
- Davis, Tenney L. (1943), The Chemistry of Powder and Explosives, II, New York: John Wiley & Sons Inc.
- Elderfield, Robert C. (1960), Werner Emanual Bachmann: 1901-1951 (PDF), Washington DC: National Academy of Sciences
- Gartz, Jochen (2007), Vom griechischen Feuer zum Dynamit: eine Kulturgeschichte der Explosivstoffe (From Greek fire to dynamite: A cultural history of explosives) (на језику: German), Hamburg: E. S. Mittler & Sohn, ISBN 978-3-8132-0867-2
- Gilman, Henry (1953), „The Chemistry of Explosives”, Organic Chemistry an Advanced Treatise, III, Wiley; Chapman & Hall, стр. 985—986
- Hale, George C. (3. 11. 1925), „The Nitration of Hexamethylenetetramine”, Journal of the American Chemical Society, 47 (11): 2754—2763, doi:10.1021/ja01688a017
- Hampton, L. D. (15. 6. 1960), The Development of RDX Composition CH-6 (PDF), White Oak, MD: U. S. Naval Ordnance Laboratory, NavOrd Report 680
- DE 104280, Henning, Georg Friedrich, issued 14. 6. 1899..
- GB 145791, von Herz, Edmund, "Improvements relating to Explosives", issued 17. 3. 1921.
- US 1402693, von Herz, Edmund, "Explosive", issued 3. 1. 1922.
- Hornby, William (1958), Factories and Plant, History of the Second World War: United Kingdom Civil Series, London: Her Majesty's Stationery Office; Longmans, Green and Co.
- MacDonald and Mack Partnership (1984), Final Properties Report: Newport Army Ammunition Plant (PDF), National Park Service, AD-A175 818
- Meyer, Rudolf (1987), Explosives (3rd изд.), VCH Publishers, ISBN 0-89573-600-4
- GB 595354, Schiessler, Robert Walter & James Hamilton Ross, "Method of Preparing 1.3.5. Trinitro Hexahydro S-Triazine", issued 3. 12. 1947.
- Simmons, W.H.; Forster, A.; Bowden, R. C. (1948), „The Manufacture of R.D.X. in Great Britain: Part II – Raw Materials and Ancillary Processes”, The Industrial Chemist, 24: 530—545
- Simmons, W.H.; Forster, A.; Bowden, R. C. (1948), „The Manufacture of R.D.X. in Great Britain: Part III – Production of the Explosive”, The Industrial Chemist, 24: 593—601
- Urbański, Tadeusz (1967), Chemistry and Technology of Explosives, III (First English изд.), Warszawa: PWN - Polish Scientific Publishers and Pergamon Press, OCLC 499857211. Translation by Marian Jurecki, edited by Sylvia Laverton. See also ISBN 978-0-08-010401-0.
- Urbański translation http://openlibrary.org/books/OL3160546M/Chemistry_and_technology_of_explosives, Macmillan, NY, 1964, ISBN 0-08-026206-6.
- Department of the Army Technical Manual TM 9-1300-214: Military Explosives. Headquarters, Department of the Army (United States).
Spoljašnje veze[уреди]
- NLM Hazardous Substances Databank (US) – Cyclonite (RDX)
- GlobalSecurity.org, Explosives - Compositions, Alexandria, VA: GlobalSecurity.org, Приступљено 1. 9. 2010
