Terpinolenska sintaza

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Terpinolenska sintaza
Identifikatori
EC broj 4.2.3.113
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB structures

Terpinolenska sintaza (EC 4.2.3.113, ag9, PmeTPS2, LaLIMS_RR) je enzim sa sistematskim imenom geranil-difosfat difosfat-lijaza (ciklizacija, formira terpinolen).[1][2][3][4][5] Ovaj enzim katalizuje sledeću hemijsku reakciju

geranil difosfat \rightleftharpoons terpinolen + difosfat

Za dejstvo ovog enzima je neophodan jon Mg2+.

Reference[уреди]

  1. ^ Croteau, R. and Satterwhite, D.M. (1989). „Biosynthesis of monoterpenes. Stereochemical implications of acyclic and monocyclic olefin formation by (+)- and (-)-pinene cyclases from sage“. J. Biol. Chem. 264: 15309-15315. PMID 2768265. 
  2. ^ Bohlmann, J., Phillips, M., Ramachandiran, V., Katoh, S. and Croteau, R. (1999). „cDNA cloning, characterization, and functional expression of four new monoterpene synthase members of the Tpsd gene family from grand fir (Abies grandis)“. Arch. Biochem. Biophys. 368: 232-243. PMID 10441373. 
  3. ^ Faldt, J., Martin, D., Miller, B., Rawat, S. and Bohlmann, J. (2003). „Traumatic resin defense in Norway spruce (Picea abies): methyl jasmonate-induced terpene synthase gene expression, and cDNA cloning and functional characterization of (+)-3-carene synthase“. Plant Mol. Biol. 51: 119-133. PMID 12602896. 
  4. ^ Huber, D.P.W., Philippe, R.N., Godard, K.-A., Sturrock, R.N. and Bohlmann, J. (2005). „Characterization of four terpene synthase cDNAs from methyl jasmonate-induced Douglas-fir, Pseudotsuga menziesii“. Phytochemistry 66: 1427-1439. PMID 15921711. 
  5. ^ Landmann, C., Fink, B., Festner, M., Dregus, M., Engel, K.H. and Schwab, W. (2007). „Cloning and functional characterization of three terpene synthases from lavender (Lavandula angustifolia)“. Arch. Biochem. Biophys. 465: 417-429. PMID 17662687. 

Literatura[уреди]

Spoljašnje veze[уреди]