1,3-Diaminopropan

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1,3-Diaminopropan
Skeletal formula of 1,3-diaminopropane
Nazivi
IUPAC naziv
Propan-1,3-diamin
Drugi nazivi
  • Propandiamin
  • 1,3-Propilendiamin
  • Trimetilendiamin
Identifikacija
3D model (Jmol)
3DMet B00214
Abrevijacija TMEDA
Bajlštajn 605277
ChEBI
ChemSpider
ECHA InfoCard 100.003.367
EC broj 203-702-7
Gmelin Referenca 1298
KEGG[1]
MeSH trimethylenediamine
RTECS TX6825000
UN broj 2922
Svojstva
C3H10N2
Molarna masa 74,13 g·mol−1
Agregatno stanje Bezbojna tečnost
Miris Ima miris ribe, amonijaka
Gustina 888 mg mL−1
Tačka topljenja 25.842 °C; 46.547 °F; 26.115 K
Tačka ključanja 3.859 °C; 6.978 °F; 4.132 K
log P −1,4
Napon pare <1,1 kPa (na 20 °C)
Indeks refrakcije (nD) 1,458
Opasnosti
GHS grafikoni The flame pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) The corrosion pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) The skull-and-crossbones pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
GHS signalna reč Opasnost
H226, H302, H310, H314
P280, P302+350, P305+351+338, P310
Toxic T Corrosive C
R-oznake R10, R22, R24, R35
S-oznake S26, S36/37/39, S45
Tačka paljenja 51 °C (124 °F; 324 K)
350 °C (662 °F; 623 K)
Eksplozivni limiti 2.8–15.2%
Letalna doza ili koncentracija (LD, LC):
LD50 (LD50)
  • 177 mg kg−1 (dermalno, zec)
  • 700 mg kg−1 (oralno, pacov)
Srodna jedinjenja
Srodne alkanamini
Srodna jedinjenja
2-Metil-2-nitrozopropan
Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje materijala (na 25 °C [77 °F], 100 kPa).
ДаY verifikuj (šta je ДаYНеН ?)
Reference infokutije

1,3-Diaminopropan je jednostavni amin. Kalijumova so se koristi u alkin ziper reakciji, objavljenoj 1975.[4]

Reference[уреди]

  1. Joanne Wixon; Douglas Kell (2000). „Website Review: The Kyoto Encyclopedia of Genes and Genomes — KEGG”. Yeast. 17 (1): 48—55. doi:10.1002/(SICI)1097-0061(200004)17:1<48::AID-YEA2>3.0.CO;2-H. 
  2. Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today. 15 (23-24): 1052—7. PMID 20970519. doi:10.1016/j.drudis.2010.10.003.  edit
  3. Evan E. Bolton; Yanli Wang; Paul A. Thiessen; Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry. 4: 217—241. doi:10.1016/S1574-1400(08)00012-1. 
  4. C. A. Brown and A. Yamashita (1975). „Saline hydrides 2and superbases in organic reactions. IX. Acetylene zipper. Exceptionally facile contrathermodynamic multipositional isomeriazation of alkynes with potassium 3-aminopropylamide”. J. Am. Chem. Soc. 97 (4): 891—892. doi:10.1021/ja00837a034.