1,3-Diaminopropan

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1,3-Diaminopropan
IUPAC ime
Drugi nazivi
  • Propandiamin
  • 1,3-Propilendiamin
  • Trimetilendiamin
Identifikacija
Abrevijacija TMEDA
CAS registarski broj 109-76-2 ДаY
PubChem[1][2] 428
ChemSpider[3] 415 ДаY
EINECS broj 203-702-7
UN broj 2922
KEGG[4] C00986
MeSH trimethylenediamine
ChEBI 15725
ChEMBL[5] CHEMBL174324 ДаY
RTECS TX6825000
Bajlštajn 605277
Gmelin Referenca 1298
3DMet B00214
Jmol-3D slike Slika 1
Svojstva
Molekulska formula C3H10N2
Molarna masa 74.12 g mol−1
Agregatno stanje Bezbojna tečnost
Miris Ima miris ribe, amonijaka
Gustina 888 mg mL−1
Tačka topljenja

-12 °C, 261.15 K, 10 °F

Tačka ključanja

140 °C, 413.2 K, 284 °F

log P −1,4
Napon pare <1,1 kPa (na 20 °C)
Indeks refrakcije (nD) 1,458
Hazardi
GHS grafikoni The flame pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) The corrosion pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) The skull-and-crossbones pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
GHS signalna reč Opasnost
H226, H302, H310, H314
P280, P302+350, P305+351+338, P310
Toxic T Corrosive C
R-oznake R10, R22, R24, R35
S-oznake S26, S36/37/39, S45
Tačka paljenja 51 °C (124 °F; 324 K)
350 °C (662 °F; 623 K)
Eksplozivni limiti 2.8–15.2%
Letalna doza ili koncentracija (LD, LC):
LD50 (LD50)
  • 177 mg kg−1 (dermalno, zec)
  • 700 mg kg−1 (oralno, pacov)
Srodna jedinjenja
Srodne alkanamini
Srodna jedinjenja
2-Metil-2-nitrozopropan

 ДаY (šta je ovo?)   (verifikuj)

Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje (25 °C, 100 kPa) materijala

1,3-Diaminopropan je jednostavni amin. Kalijumova so se koristi u alkin ziper reakciji, objavljenoj 1975.[6]

Reference[уреди]

  1. Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today. 15 (23-24): 1052—7. doi:10.1016/j.drudis.2010.10.003. PMID 20970519.  edit
  2. Evan E. Bolton; Yanli Wang; Paul A. Thiessen; Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry. 4: 217—241. doi:10.1016/S1574-1400(08)00012-1. 
  3. Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform. 2 (1): 3. doi:10.1186/1758-2946-2-3. PMID 20331846.  edit
  4. Joanne Wixon; Douglas Kell (2000). „Website Review: The Kyoto Encyclopedia of Genes and Genomes — KEGG”. Yeast. 17 (1): 48—55. doi:10.1002/(SICI)1097-0061(200004)17:1<48::AID-YEA2>3.0.CO;2-H. 
  5. Gaulton A, Bellis LJ, Bento AP, Chambers J, Davies M, Hersey A, Light Y, McGlinchey S, Michalovich D, Al-Lazikani B, Overington JP (2012). „ChEMBL: a large-scale bioactivity database for drug discovery”. Nucleic Acids Res. 40 (Database issue): D1100—7. doi:10.1093/nar/gkr777. PMID 21948594.  edit
  6. C. A. Brown and A. Yamashita (1975). „Saline hydrides 2and superbases in organic reactions. IX. Acetylene zipper. Exceptionally facile contrathermodynamic multipositional isomeriazation of alkynes with potassium 3-aminopropylamide”. J. Am. Chem. Soc. 97 (4): 891—892. doi:10.1021/ja00837a034.